Smart windows could block brightness and harness light

Who needs curtains? One day, you could block out afternoon glare and heat with changeable windows that absorb sunshine to charge your electronics.

A high-tech prototype panel described online January 22 in Nature Materials, switches between transparent pane and dark-tinted solar cell. The layer in the panel that’s responsible for soaking up sun has atoms that only arrange themselves into a light-absorbing crystal structure at high temperatures. When heated, these atoms form a dark-tinted crystal known as a perovskite, a new darling of the solar cell industry (SN: 8/5/17, p. 22).
Letian Dou, a chemical engineer at Purdue University, and colleagues were only able to form these light-harvesting crystals in their solar cells by cranking the heat to 105° Celsius, much hotter than your average sun-blasted window. The team is working to lower that threshold to below 70° C so that sunshine alone would trigger the switch.

Currently, the perovskite’s atoms stay locked in crystal configuration until exposed to moisture, which jumbles up the atoms and turns the material transparent again. The researchers still need to find a way to deactivate the solar cell mode without needing a spray bottle of water on hand.

The technology could someday be used for windshields that recharge electric vehicles and keep a parked car’s interior cool while the sun bakes outside.

Strong winds send migrating seal pups on lengthier trips

PORTLAND, Ore. — Native American fishermen in Alaska have long said that seal pups go with the wind rather than struggle against it. Now, a new study confirms that wisdom. Migrating northern fur seal pups travel hundreds of kilometers farther in blustery years than in milder years, researchers reported February 14 at the American Geophysical Union’s Ocean Sciences meeting. Those epic journeys may be linked to pup deaths.

At 4 months old, the pups are weaned and begin a voyage from the Pribilof Islands of Alaska through the Bering Sea and North Pacific Ocean that can last for 20 months before they return to the islands. Physical oceanographer Noel Pelland and colleagues compared the migrations of 168 seal pups tagged in five different years from 1996 to 2015 with winds matching the pups’ first migration years. Winds were simulated using data from the U.S. National Centers for Environmental Prediction.
On average, the pups moved farther downwind when wind speeds were higher, and tended to move to the right of the wind direction — likely following wind-driven ocean currents. Tagging data lasted 130 days on average, but whether the pups died or the tags fell off is unknown. That makes it difficult to draw a definitive link to mortality, says Pelland of the National Oceanographic and Atmospheric Administration’s Alaska Fisheries Science Center in Seattle.

Still, the lengthier, more physically challenging journeys in some years may explain why populations of these northern fur seals — considered “depleted” under the Marine Mammal Protection Act — have not rebounded in recent decades despite a hunting ban.

Next the team plans to simulate seal pup migrations and compare those modeled journeys with decades of wind records. Hunting records from the mid-20th century include data on seal mortality, Pelland says; comparing these data might help identify a direct link between winds and pup deaths.

Cave art suggests Neandertals were ancient humans’ mental equals

Neandertals drew on cave walls and made personal ornaments long before encountering Homo sapiens, two new studies find. These discoveries paint bulky, jut-jawed Neandertals as the mental equals of ancient humans, scientists say.

Rock art depicting abstract shapes and hand stencils in three Spanish caves dates back to at least 64,800 years ago, researchers report in the Feb. 23 Science. If these new estimates hold up, the Spanish finds become the world’s oldest known examples of cave art, preceding evidence of humans’ arrival in Europe by at least 20,000 years (SN Online: 11/2/11).
The finds raise the possibility that “Neandertals took modern humans into caves and showed them how to paint,” says archaeologist Francesco d’Errico of the University of Bordeaux in France.

Personal ornaments previously found at a coastal cave in southeastern Spain are older than the cave art, dating to around 120,000 to 115,000 years ago, scientists report February 22 in Science Advances. Only Neandertals inhabited Europe at that time. Those artifacts consist of pigment-stained seashells with artificial holes, presumably for use as necklaces, and seashells containing remnants of pigment mixtures, say geochronologist Dirk Hoffmann of the Max Planck Institute for Evolutionary Anthropology in Leipzig, Germany, and colleagues. Hoffmann is also an author of the cave art study. The new findings join previous reports of potentially symbolic Neandertal artifacts, such as a possible necklace made from eagle claws (SN: 4/18/15, p. 7) and bird-feather decorations.
If Neandertals did have the capacity for symbolic thinking — crucial for using drawings or language to represent ideas and objects — that ability may have developed at least 500,000 years ago in an ancestor shared with humans, the two research teams propose.
“Neandertal social life was as complex as that of [contemporaneous] humans in Africa,” says archaeologist João Zilhão of the University of Barcelona, an author of both papers.

But some scientists view the new findings cautiously. Neandertals communicated in sophisticated ways, but few clearly symbolic artifacts have been linked to them, says archaeologist Nicholas Conard of the University of Tübingen in Germany. “If Neandertals regularly produced paintings or similar kinds of symbolic artifacts, researchers will eventually demonstrate it at multiple sites,” he says.

Analyses of thin mineral deposits partly covering painted cave areas provided minimum age estimates for the art, based on known decay rates of radioactive uranium in the rock. One red, rectangular painting dates to at least 64,800 years ago. One of several hand stencils in a second cave dates to at least 66,700 years ago. And in a third cave, patches of red paint were applied to the walls at least 65,500 years ago, with more paintings added over a period of 25,000 years or more — signaling a long Neandertal tradition of cave art, the researchers say.
Many dated deposits at the Spanish cave art sites contain rock particles from external sources that can throw off age estimates. The researchers statistically corrected for such contamination, “but whether that is sufficient enough remains to be seen,” says archaeologist Katerina Douka of the Max Planck Institute for the Science of Human History in Jena, Germany.

At the coastal cave, dating relied on a one-two punch: uranium analyses of rock partly covering shell-bearing sediment and geologic estimates of when ancient sea levels declined enough to allow entry into the chamber.

Still, it is “nearly impossible” to generate accurate age estimates of rock art based on uranium measures alone, researchers concluded in 2017 in Quaternary International. Depending on shifting cave conditions and varying amounts of uranium drainage from mineral deposits, this method can over- or underestimate when rock art was created, the scientists argued. Other researchers defend this technique as providing valuable minimum and maximum age estimates for rock art.

If the new dates for the Spanish cave art are confirmed, they could indicate that Neandertals and H. sapiens exchanged artistic traditions earlier than previously thought, says paleoanthropologist Chris Stringer of the Natural History Museum in London, who was not involved in the studies. Members of both species may have reached western Asia and intermingled during rainy periods between 244,000 and 190,000 years ago, Stringer proposes (SN: 2/17/18, p. 6).